59807-87-3

Basic information

• Product Name: Cyclohexanol, 1-[(phenylsulfonyl)methyl]-
• CAS NO: 59807-87-3
• Molecular Formula: C13H18O3S
• Molecular Weight: 254.35
• Mol File: 59807-87-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 1-[(phenylsulfonyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 1-[(phenylsulfonyl)methyl]-(59807-87-3)
• EPA Substance Registry System: Cyclohexanol, 1-[(phenylsulfonyl)methyl]-(59807-87-3)

Safety Data

• Hazardous Substances Data: 59807-87-3(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 13307-75-0 (phenylthio)methyllithium 
• 41719-09-9 Iodomethyl phenyl sulfoxide 
• 195371-24-5 1-(Benzenesulfonyl-bromo-methyl)-cyclohexanol 
• 91525-46-1 1-(Benzenesulfinyl-iodo-methyl)-cyclohexanol 
• 97364-12-0 C₆H₅S(O)2CH₂Ti(OCH(CH₃)2)3 
• 3406-02-8 bis(phenylsulfonyl)methane 
• 3112-85-4 methylphenylsulfonate 

Downstream Products

• 49639-03-4 (cyclohex-1-enyl)methyl phenyl sulfone 
• 90020-44-3 (cyclohexylidene)methyl phenyl sulfone 
• 68826-56-2 Acetic acid (1S,2R)-2-benzenesulfonyl-1,2-di-cyclohex-1-enyl-ethyl ester 
• 68826-56-2 Acetic acid (1R,2R)-2-benzenesulfonyl-1,2-di-cyclohex-1-enyl-ethyl ester 
• 156049-95-5 trans-1,2-di-cyclohex-1-enyl-ethene 
• 68826-53-9 (E)-(2-(cyclohex-1-en-1-yl)vinyl)benzene 
• 100229-88-7 1-(cyclohexen-1-yl)-1-(phenylsulfonyl)ethane 

Relevant articles and documents

A simple reduction of α-bromosulfones by cat.(PhSe)2/NaBH4

Reduction of α-bromosulfones 1, 5, 13-16 by cat.(PhSe)2/NaBH4 occurred site-selectively in high yields. This reduction of 1,3- or 1,4-dibromobis(sulfone) 21 and 25 was applied to intramolecular coupling reactions to give the three- and four-membered carbocycles 26-28.

Chemo-, Regio-, and Diastereoselective Alkylation via Lewis Acid Promoted Substitutions of Sulfones

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IODOMETHYL PHENYL SULFOXIDE: REACTIVITY AND SYNTHETIC APPLICATIONS

Lithio iodomethyl phenyl sulfoxides reacted with alkyl halides and carbonyl compounds to give adducts in good to moderate yields.Solvolysis of the carbonyl adducts led to sulfones or the ring expanded product.