59847-24-4

Upstream product

• 98-88-4 benzoyl chloride 
• 7182-08-3 4-(1-cyclohepten-1-yl)morpholine 

Downstream Products

• 133147-61-2 (3-chloro-2-morpholino-1-cyclohepten-3-yl)-phenyl-methanone 
• 59847-20-0 2-benzoyloxycycloheptanone 
• 911797-29-0 4-morpholino-2-phenyl-1-oxa-spiro<2,5>-4-nonene-2-carbonitrile 
• 59847-30-2 Carbonic acid 2-benzoyl-cyclohept-1-enyl ester methyl ester 

Relevant academic research and scientific papers

FUNCTIONALIZED CHLOROENAMINES IN AMINOCYCLOPROPANE SYNTHESIS - V. SYNTHESIS AND REACTIONS OF AMINOCYCLOPROPYLKETONES

Conjugated acylated chloroenamines 5A,C were available by chlorination of mixtures of acylated enamines 8A,C/9A,C by NCS at 0 deg C.Nonconjugated chloroenamines 10Aa and 10Ba could be obtained by NCS-chlorination of the conjugated acylenamines 9A,B at low temperature.Reaction of 5Aa-5Ac, 5Ae, 5Af with cyanide produced morpholinocyclopropylketones 11A.In two cases aminofurans 12Ad and 12Ca resulted as products of this reaction.More generally amino-aryl-furans 12 were formed by thermolysis of the aryl-cyclopropylketones 11.Amino-alkyl-furans as 12Ae and 12Af only could be trapped by a Diels-Alder reaction leading to 16Ae and 16Af.Epoxyenamines 29A,B unexpectedly were produced from the interaction of cyanide with the chloroenamines 10Aa and 10Ba.