60031-37-0Relevant academic research and scientific papers
Zincation of 4,4-dimethyloxazoline using TMPZnCl·LiCl. A new preparation of 2-aryloxazolines
Haas, Diana,Hofmayer, Maximilian S.,Bresser, Tomke,Knochel, Paul
supporting information, p. 6415 - 6417 (2015/04/14)
The metalation of 4,4-dimethyloxazoline using TMPZnCl·LiCl provides a stable 2-zincated oxazolinyl reagent which readily undergoes palladium-catalyzed Negishi cross-couplings allowing a new access to 2-aryloxazolines. Cu-mediated acylation and allylation reactions also proceed in good yields. This journal is
Terminal oxazolinyloxiranes: synthesis, reaction with amines and regioselective β-lithiation
Degennaro, Leonardo,Capriati, Vito,Carlucci, Claudia,Florio, Saverio,Luisi, Renzo,Nuzzo, Irene,Cuocci, Corrado
experimental part, p. 8745 - 8755 (2009/12/28)
The synthesis of terminal oxazolinyloxiranes, even in enantioenriched form, has been performed by Darzens-type reaction of lithiated chloroalkyloxazolines with benzotriazolylmethanol (BtCH2OH) or by chloromethylation of 2-acyl-2-oxazolines. The
