60034-57-3

Basic information

• Product Name: Benzene, [[(1R,2R)-2-chloro-3-cyclopenten-1-yl]thio]-, rel-
• CAS NO: 60034-57-3
• Molecular Formula: C11H11ClS
• Molecular Weight: 210.727
• Mol File: 60034-57-3.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [[(1R,2R)-2-chloro-3-cyclopenten-1-yl]thio]-, rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(1R,2R)-2-chloro-3-cyclopenten-1-yl]thio]-, rel-(60034-57-3)
• EPA Substance Registry System: Benzene, [[(1R,2R)-2-chloro-3-cyclopenten-1-yl]thio]-, rel-(60034-57-3)

Safety Data

• Hazardous Substances Data: 60034-57-3(Hazardous Substances Data)

Upstream product

• 4837-31-4 4-Phenylsulfanyl-morpholine 
• 542-92-7 cyclopenta-1,3-diene 
• 54815-45-1 ethyl benzenesulfenate 
• 108-98-5 thiophenol 
• 931-59-9 benzenesulfenyl chloride 

Downstream Products

• 60034-64-2 trans-4-chloro-5-(phenylsulfonyl)-2-cyclopentene 
• 60034-53-9 cis-3,5-Bis(phenylsulfonyl)cyclopenten 
• 119472-53-6 (1R,7S,10R)-10-Benzenesulfonyl-10-methyl-4-phenyl-2,4,6-triaza-tricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione 
• 60034-53-9 trans-3,5-Bis(phenylsulfonyl)cyclopenten 
• 119472-52-5 (1R,4R,5R)-4-Benzenesulfonyl-4-methyl-6-oxa-bicyclo[3.1.0]hex-2-ene 
• 119472-49-0 (1-Methyl-cyclopenta-2,4-dienesulfonyl)-benzene 
• 87892-94-2 4-(2-Benzenesulfonyl-cyclopenta-1,4-dienyl)-butan-2-one 
• 87892-93-1 4-(5-Benzenesulfonyl-cyclopenta-1,3-dienyl)-butan-2-one 
• 87892-92-0 4-(1-phenylsulphonylcyclopenta-2,4-dienyl)butan-2-one 
• 87892-91-9 1-phenylsulphonylcyclopentadiene 
• 105064-22-0 5-[(1R,2S,4S,5R)-2-(3-Azido-propyl)-2-benzenesulfonyl-4,5-diisopropoxy-cyclopentyl]-6-vinyl-benzo[1,3]dioxole 
• 105064-23-1 (2S,3R,4R,5S)-rac-5-(3-azidopropyl)-2,3-dihydroxy-5-(phenylsulfonyl)-4-<6-vinyl-3,4-(methylenedioxy)phenyl>cyclopentane 
• 105064-20-8 4-chloro-2,3-(isopropylidenedioxy)-5-(phenylsulfonyl)cyclopentane 
• 105064-21-9 (2S,3R)-rac-2,3-(isopropylidenedioxy)-5-(phenylsulfonyl)-4-cyclopentene 

Relevant articles and documents

A new method for the activation of ethyl benzenesulfenate in electrophilic addition reactions

Reactions of unsaturated compounds with the PhSOEt-SOHal2 and PhSOEt-Me3SiHal systems (Hal = Cl or Br) were proposed as a new route to haloalkyl phenyl sulfides. With acyclic and mono- and bicyclic alkenes and dienes as examples, the

Halosulfenylation of Conjugated Dienes with Arylsulfenamides in the Presence of Phosphorus Oxyhalides

Electrophilic sulfenylation of cyclic and open-chain conjugated dienes effected by a system arylsulfenamide-phosphorus oxyhalide was investigated. The initially formed adducts of 1,2-halosulfenylation in the course of the reaction and also at storage and chromatograqphic purification on silica gel undergo quantitative isomerization into a mixture of stereoisomeric products of 1,4-addition. The effect of halogen nature and the character of substituents in the benzene ring of arenesulfenamide on the addition rate of sulfenamides activated by phosphorus oxyhalides to open-chain and cyclic conjugated dienes and isomerization rate of the arising 1,2-adducts was examined.

SYNTHESIS AND STEREOSELECTIVE CHEMISTRY OF A NOVEL CYCLOPENTADIENYL SULPHONE

The synthesis of a novel cyclopentadienyl sulphone (3) has been achieved by two routes, one of which involves a previously unsuccessful alkylation of the sulphone carbanion(4), some preliminary chemistry of the new diene is also reported.

Rapid Access to a Series of Highly Functionalized α,β-Unsaturated Cyclopentenones. A Caveat on Aminospirocyclization

Conjugate addition of a series of functionalized aryllithium reagents to cyclopentenyl sulfones 9 and 17 results in α-sulfonyl anion intermediates taht are further alkylated to afford triply converged adducts 12a-c and 19.Refunctionalization of these adducts provides α,β-unsaturated cyclopentenones 4a-c and 21 in high overall yields.Attempted intramolecular Michael addition of these (γ-aminopropyl)cyclopentenones to produce the spiro ring system was unsuccessful.

An Investigation of the Chemistry of Phenylsulphonylcyclopentadiene

Phenylsulphonylcyclopentadiene (7) exists mainly as the 1-isomer, and the assigned structure of its dimer (6) has been corroborated by n.m.r. decoupling experiments.Both the diene (7) and its cyclopentadienide anion (8) were unusually unreactive, although