60068-17-9

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 118-93-4 o-hydroxyacetophenone 

Downstream Products

• 60068-21-5 1-Trimethylsilanyloxy-2-(1-trimethylsilanyloxy-cyclopropyl)-benzene 
• 130984-33-7 3-hydroxy-1-(2-hydroxyphenyl)-5-phenyl-1-pentanone 
• 7169-34-8 3-oxo-2,3-dihydrobenzo[b]furan 
• 17375-96-1 2-hydroxy-1-(2-hydroxyphenyl)ethanone 
• 57753-08-9 1,4-di(2'-hydroxyphenyl)butane-1,4-dione 
• 118-93-4 o-hydroxyacetophenone 
• 130984-35-9 2-(1-hydroxycyclohexyl)-1-(2-hydroxyphenyl)ethanone 
• 130984-32-6 3-hydroxy-1-(2-hydroxyphenyl)-4-phenyl-1-butanone 
• 130160-93-9 C₂₀H₂₉NO₃Si₂ 
• 60068-23-7 2-(1-Hydroxy-cyclopropyl)-phenol 
• 60068-25-9 2-(1-Chloro-cyclopropyl)-phenol 
• 130984-36-0 2,3-dihydro-2-(phenylmethyl)-4H-1-benzopyran-4-one 
• 64838-30-8 2,3-dihydro-2-(2-phenylethyl)-4H-1-benzopyran-4-one 
• 127841-40-1 1-(2-hydroxyphenyl)-3,3-dimethoxy-1-propanone 

Relevant academic research and scientific papers

Chemistry of aldolate dianions. β-silyloxy silyl enol ethers as bifunctional nucleophilic equivalents for oxygen heterocycle synthesis

A variety of β-silyloxy silyl enol ethers (3) are easily produced by double deprotonation of readily available β-hydroxyketones. These substances undergo cyclization reactions with dioxenium cations to provide 2-alkoxy-tetrahydropyranones, thus confirming the use of 3 as bifunctional reagents for oxygen heterocycle synthesis.

CYCLOADDITION OF SILYLENE PROTECTING DIHYDROXYSTYRENE DERIVED FROM ORTHO-HYDROXYACETOPHENONE: ONE-STEP SYNTHESIS OF PERI-HYDROXYLATED POLYCICLIC COMPOUNDS

Thermal treatment of the silylene protecting dihydroxystyrene derived from o-hydroxyacetophenone with dienophiles caused a cycloaddition to give the corresponding peri-hydroxylated polycyclic aromatic compounds in a single step.