600698-57-5Relevant academic research and scientific papers
Hydration of nitrosylruthenium acetylide complexes having a tris(pyrazol-1-yl)borate in the presence of protic acid: Formation of ketonyl and acyl complexes
Arikawa, Yasuhiro,Nishimura, Yoshimasa,Kawano, Hiroyuki,Onishi, Masayoshi
, p. 3354 - 3356 (2003)
The hydration of nitrosylruthenium acetylide complexes having a tris(pyrazol-1-yl)borate in the presence of protic acid was studied. The protonation of the monoacetylide complexes caused a hydration reaction, producing ketonyl complexes and unsaturated acyl complexes. Spectroscopic data confirmed the ketonyl complex and the α,β-unsaturated acyl complexes.
