600726-49-6Relevant academic research and scientific papers
Diastereoselective diallylation of various butane-2,3-diacetals by allylsilane
Mariet, Natacha,Ibrahim-Ouali, Malika,Santelli, Maurice
, p. 5315 - 5317 (2003)
Five butane-2,3-diacetals obtained from the reaction of 1,2-diols and methanol with biacetyl have been treated with allylsilane in the presence of titanium tetrachloride to afford bis-allyldioxanes as single diastereoisomers.
Dialkylation of various butane-2,3-diacetals using allylsilane and 1,8-bis(trimethylsilyl)-2,6-octadiene
Mariet, Natacha,Pellissier, Helene,Ibrahim-Ouali, Malika,Santelli, Maurice
, p. 2679 - 2691 (2007/10/03)
We report in this paper a greatly improved procedure for the formation of a range of 1-acetyl-1-methyl-2,5-divinylcyclopentanes from 1,8- bis(trimethylsilyl)octa-2,6-diene (BISTRO) and 1,2-diacetals prepared directly from biacetyl. These 1-acetyl-1-methyl
