60154-95-2Relevant articles and documents
Silenes as novel synthetic reagents: Identification of a practical method for silene generation and trapping
Berry, Malcolm B.,Griffiths, Russell J.,Sanganee, Mahesh J.,Steel, Patrick G.,Whelligan, Daniel K.
, p. 2381 - 2392 (2007/10/03)
The elucidation of a robust and reliable sequence for the generation of highly reactive transient silenes from simple aldehydes is described. The key step involves a silyl-modified Peterson olefination which critically depends on the presence of a sub-sto
Silenes in organic synthesis 1: Diastereoselectivity in the siloxysilene-diene Diels-Alder cycloaddition
Batsanov, Andrei S.,Clarkson, Ian M.,Howard, Judith A. K.,Steel, Patrick G.
, p. 2491 - 2494 (2007/10/03)
The siloxysilene (3) derived from thermolysis of benzoylpolysilane undergoes a facile in situ cycloaddition with a range of dienes to produce the corresponding cycloadducts with modest to good diastereoselectivity.