60254-10-6Relevant articles and documents
Synthesis and characterisation of the water soluble bis-phosphine complex [Ru(η6-cymene)(PPh2(o-C6H 4O)-κ2-P,O)(pta)]+ and an investigation of its cytotoxic effects
Renfrew, Anna K.,Egger, Alexander E.,Scopelliti, Rosario,Hartinger, Christian G.,Dyson, Paul J.
, p. 1144 - 1150 (2010)
Metal complexes bearing phosphine ligands are attracting increasing attention for their applications in medicinal chemistry. In particular, organometallic ruthenium-phosphine complexes have been found to exhibit promising antitumour activity. The synthesis, anticancer activity and reactivity of a novel bis-phosphine complex, [Ru(η6-cymene)(PPh 2(o-C6H4O)-κ2-P,O)(pta)]Cl (pta = 1,3,5-triaza-7-phosphatricyclo[3.3.1.1.]decane), is presented. The complex appears to exhibit its anticancer effect via a different mechanism to other ruthenium-arene pta complexes with labile co-ligands.
Electrophilic d0 Cations of Group 4 Metals (M = Ti, Zr, Hf) Derived from Monopentafulvene Complexes: Direct Formation of Tridentate Cp, O, P -Ligands
Fischer, Malte,Schaper, Raoul,Jaugstetter, Maximilian,Schmidtmann, Marc,Beckhaus, Rüdiger
supporting information, p. 1192 - 1205 (2018/04/17)
The reactions of the monopentafulvene complexes Ti1a and Ti1b with the general formula [CpTi(Cl)(π-η5:σ-η1-C5H4=CR2)] (R = p-tolyl (Ti1a); CR2 = adamantylidene (Ti1b)) with the bidentate P,
Aryl Fluorosulfate Trapped Staudinger Reduction
Ren, Gerui,Zheng, Qinheng,Wang, Hua
supporting information, p. 1582 - 1585 (2017/04/13)
A chemoselective Staudinger reduction/sulfur(VI) fluoride exchange cascade has been developed to join two chemical segments through an aryl sulfamate ester (RNH-SO2-OAr) linkage. Aryl fluorosulfate is exploited in this work as the first tetrahe
