60278-05-9Relevant articles and documents
Bronsted Acid Mediated Direct α-Hydroxylation of Cyclic α-Branched Ketones
Shevchenko, Grigory A.,Dehn, Stefanie,List, Benjamin
, p. 2298 - 2300 (2018)
We report a Bronsted acid mediated direct α-hydroxylation of cyclic α-branched ketones via a tandem aminoxylation/N-O bond-cleavage process. Nitrosobenzene is used as the oxidant and subsequently promotes the liberation of the free alcohol. The desired pr