60294-99-7

Upstream product

• 14876-51-8 Ni(CO)CH₃C{CH₂P(C₆H₅)2}3 
• 83561-95-9 [(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂CSMe)]BPh₄ 
• 83561-99-3 [(1,1,1-tris((diphenylphosphino)methyl)ethane)Ni(S₂CNEt₂)]BPh₄ 
• 83562-00-9 (CH₃C(CH₂P(C₆H₅)2)3)Ni(S₂CS) 

Downstream Products

• 14876-51-8 Ni(CO)CH₃C{CH₂P(C₆H₅)2}3 
• 89952-75-0 Ni(((C₆H₅)2PCH₂)3CCH₃)(C₃S₂(CF₃)2) 
• 90914-28-6 {OP(C₆H₅)2CH₂C(CH₃)(CH₂P(C₆H₅)2)2}Ni(CO₃) 
• 90914-29-7 {OP(C₆H₅)2CH₂C(CH₃)(CH₂P(C₆H₅)2)2}Ni(CO₃)*0.5H₂O*C₆H₆ 
• 86567-91-1 (CH₃C(CH₂P(C₆H₅)2)3)Ni(SCN(C₆H₅))*0.5CH₂Cl₂ 

Relevant academic research and scientific papers

Reactivity of η2-CS3Me Metal Complexes as Electrophiles

The CS2 carbon atom of the η2-CS3Me ligand in the cobalt(II) and nickel(II) complexes is an electrophilic centre, susceptible to attack by nucleophil

New Metal-assisted Synthesis of Tetrakis(trifluoromethyl)tetrathiafulvalene

Replacement of the 1,3-dithiolium carbene ligand by CO or F3CCCCF3 in the complex > affords the complexes or , whereas the 1,3-dithioli

Nucleophilic attack on η2-coordinated dithio acids by hydride ion. A preliminary step in the formation of a variety of nickel complexes

The nickel(II) complexes [(triphos)Ni(S2CPEt3)](BPh4)2, [(triphos)Ni(S2CSMe)]BPh4, [(triphos)Ni-(S2COEt)]BPh4, and [(triphos)Ni(S2CNEt2)]BPh4 (triphos = 1,1,1-tris((diphenyphosphino)methyl)ethane) react with NaBH4 to give the complexes [(triphos)Ni{S2C(H)PEt3}BPh4, [(triphos)Ni(π-CS2)], {(triphos)Ni(CO)], and [(triphos)Ni(SH)], respectively. The formation of all of these compounds is suggested to proceed via nucleophilic attack by the hydride ion from NaBH4 on the electrophilic CS2 carbon atom, followed by rearrangement of the resultant adduct. In some cases the reaction is accompanied by a lowering of the metal oxidation state by one or two units.