86567-91-1Relevant academic research and scientific papers
SYNTHESIS AND CRYSTAL STRUCTURE OF THE dihapto-BONDED PHENYLISOTHIOCYANATE COMPLEX 2-SCNPh)>*0.5CH2Cl2
Bianchini, Claudio,Masi, Dante,Mealli, Carlo,Meli, Andrea
, p. C29 - C31 (1983)
The complex 2-SCNPh)> (triphos=1,1,1-tris(diphenylphosphinomethyl)ethane) is obtained from the reaction of the nickel(0) complex 2-CS2)> with phenylisothiocyanate.An X-ray crystal structure determination has shown that the nickel atom is five-coordinated by the three phosphorus atoms of triphos and the carbon and sulfur atoms of a SNCPh molecule.
