60352-71-8Relevant academic research and scientific papers
A synthesis of the quinolizidine alkaloids (±)-lasubine I and (±)-lasubine II
Bardot, Valérie,Gardette, Daniel,Gelas-Mialhe, Yvonne,Gramain, Jean-Claude,Remuson, Roland
, p. 507 - 518 (2007/10/03)
A total synthesis of (±)-lasubine I and (±)-lasubine II has been achieved in six steps from a β-hydroxyallylsilane synthon using intramolecular cyclization of allylsilane on N-acyliminium ion as a key step.
Synthetic Studies on Lythraceae Alkaloids via Cycloaddition. I. Total Synthesis of Some Simple Phenylquinolizidine Alkaloids and Ester Alkaloids 1,2)
Takano, Seiichi,Shishido, Kozo
, p. 3892 - 3899 (2007/10/02)
A general synthetic route to Lythraceae alkaloids based on a regio- and stereoselective cycloaddition reaction has been developed.The cycloaddition of the nitrone 5 with the olefins 14 and 26 gave the adducts 15 and 27 which, upon treatment with
New Approach to Lythraceae Alkaloids: Total Synthesis of (+/-)-Vertaline
Hart, David J.,Kanai, Ken-ichi
, p. 1555 - 1560 (2007/10/02)
A new approach to Lythraceae alkaloids is described within the context of a total synthesis of (+/-)-vertaline (2).The use of N-silyl imines in the preparation of benzylic amines as well as a stereoselective bicycloannelation approach to the synthesis of quinolizidinones is discussed.
General Synthetic Approach to the Quinolizidine Alkaloids via a -Cycloaddition
Takano, Seiichi,Shishido, Kozo
, p. 940 - 942 (2007/10/02)
Two naturally occurring arylquinolizidinols have been synthesized via a -cycloaddition.
