60433-18-3Relevant academic research and scientific papers
Reactions of copper(II) β-diketonates under free radical conditions. Preparation of highly congested β-diketones
Lloris, Maria E.,Galvez, Nicanor,Marquet, Jorge,Moreno-Manas, Marcial
, p. 8031 - 8042 (2007/10/02)
Copper(II) β-diketonates react with alkyl bromides under free radical conditions to give highly congested β-diketones such as 3-(1-adamantyl)-3-alkylpentane-2,4-diones. Another typical free radical reagent: benzoyl peroxide, reacts also functionalizing the intercarbonyl positions.
Regio- and Stereoselective 1,2 Wagner-Meerwein Shifts during Trifluoroacetic Acid Catalyzed Isomerization of Unsymmetrically Substituted Tricyclo2,4>heptanes
Gree, Rene,Park, Hokoon,Paquette, Leo A.
, p. 4397 - 4403 (2007/10/02)
The regioselectivity and stereoselectivity which materialize upon trifluoroacetic acid promoted isomerization of variously substituted tricyclo2,4>heptanes have been experimentally determined.The highly strained hydrocarbon substrates h
