60455-13-2Relevant academic research and scientific papers
Green Access to α-Haloalkyl and α-Halobenzyl Esters, Versatile Intermediates for the One-Pot Two-Step Synthesis of O, O ′-Diacyl Acetals Using Zinc-Based Ionic Liquid Catalyst
Fache, Fabienne,De Azpiazu, Ignasi,Pelotier, Béatrice,Piva, Olivier,Gozzi, Christel
, p. 2430 - 2434 (2019)
α-Haloalkyl and α-halobenzyl esters have been synthesized using a zinc-based ionic liquid catalyst, BMIZnCl 3. These esters can then react with acids without intermediate purification to obtain mixed O, O ′-diacyl acetals in a one-pot process.
Zn(OTf)2.6H2O catalysed acylation of aldehydes: Preparation of 1,1-diacetates and α-chloroalkyl esters
Su, Weike,Can, Jin
, p. 88 - 90 (2007/10/03)
1,1-Diacetates (acylals) and α-chloroalkyl esters were prepared from carbonyl compounds with acylating reagents in the presence of 5% mol hexaaqua zinc triflate [Zn(OTf)2.6H2O] with good yields under mild reaction conditions.
