60456-14-6

Basic information

• Product Name: Benzenepropanoic acid, a-bromo-b-methoxy-
• CAS NO: 60456-14-6
• Molecular Formula: C10H11BrO3
• Molecular Weight: 259.1
• Mol File: 60456-14-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenepropanoic acid, a-bromo-b-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoic acid, a-bromo-b-methoxy-(60456-14-6)
• EPA Substance Registry System: Benzenepropanoic acid, a-bromo-b-methoxy-(60456-14-6)

Safety Data

• Hazardous Substances Data: 60456-14-6(Hazardous Substances Data)

Upstream product

• 621-82-9 Cinnamic acid 
• 67-56-1 methanol 
• 140-10-3 (E)-3-phenylacrylic acid 
• 7732-18-5 water 
• 7726-95-6 bromine 
• 60456-13-5 2-bromo-3-methoxy-3-phenyl-propionic acid methyl ester 
• 140-10-3 cis-cinnamic acid 
• 103-26-4 methyl cinnamate 

Downstream Products

• 100370-32-9 (2RS,3RS)-2-amino-3-methoxy-3-phenyl-propionic acid ethyl ester 
• 99986-20-6 (2RS,3RS)-3-methoxy-2-methylamino-3-phenyl-propionic acid 
• 52834-89-6 (2RS,3RS)-2-amino-3-methoxy-3-phenyl-propionic acid 
• 99076-17-2 (2RS,3SR)-3-hydroxy-2-methylamino-3-phenyl-propionic acid 

Relevant articles and documents

Methoxybromination of Cinnamic Acid by N-Bromosuccinimide

With cinnamic acid in aqeous methanol N-bromosuccinimide yields 2-bromo-3-methoxy-3-phenyl-propionic acid.It is a second-order reaction independent of +> at moderately high +>.At low +> the rate increases with decrea

Methoxybromination of Cinnamic Acid by IV-Bromosuccinimide

With cinnamic acid in aqueous methanol iV-bromosuccinimide yields 2-bromo-3-methoxy-3-phenyl-propionic acid. It is a second-order reaction independent of [H+] at moderately high [H+]. At low [H+] the rate increases with decrease in [H+]. The reaction is inhibited by succinimide. The reaction rate decreases with increase in methanol content of the medium. Mechanistic pathways of the reaction are discussed and a rate equation is derived.