60470-15-7

Basic information

• Product Name: benzyl tert-butyl carbonate
• Synonyms: benzyl tert-butyl carbonate
• CAS NO: 60470-15-7
• Molecular Weight: 208.257
• Mol File: 60470-15-7.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: benzyl tert-butyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl tert-butyl carbonate(60470-15-7)
• EPA Substance Registry System: benzyl tert-butyl carbonate(60470-15-7)

Safety Data

• Hazardous Substances Data: 60470-15-7(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 507-19-7 t-butyl bromide 
• 124-38-9 carbon dioxide 
• 100-51-6 benzyl alcohol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 445-29-4 o-fluoro-benzoic acid 
• 121-92-6 3-nitrobenzoic acid 

Downstream Products

• 705-58-8 3-methyl-1-phenyl-2-butanol 
• 35863-45-7 2,2-dimethyl-3-phenylpropanenitrile 
• 1320337-31-2 benzyl 4,6-di-O-acetyl-2,3-dideoxy-3-ethylthio-α-D-arabino-hexopyranoside 
• 1037210-08-4 bis-CBz-cyclopamine 
• 34577-40-7 3-benzyl-3-pentanol 
• 100-86-7 2-Methyl-1-phenyl-2-propanol 
• 105735-62-4 3,3-dimethyl-1-phenyl-2-butanol 
• 1944-01-0 1-benzylcyclohexan-1-ol 
• 870-46-2 t-butoxycarbonylhydrazine 

Relevant articles and documents

The Guanidine-Promoted Direct Synthesis of Open-Chained Carbonates

In order to reduce CO2 accumulation in the atmosphere, chemical fixation methodologies were developed and proved to be promising. In general, CO2 was turned into cyclic carbonates by cycloaddition with epoxides. However, the cyclic carbonates need to be converted into open-chained carbonates by transesterification for industrial usage, which results in wasted energy and materials. Herein, we report a process catalyzed by tetramethylguanidine (TMG) to afford linear carbonates directly. This process is greener and shows potential for industrial applications.

PROCESS FOR THE CATALYTIC DIRECTED CLEAVAGE OF AMIDE-CONTAINING COMPOUNDS

The present invention relates to a catalytic method for the conversion of amide-containing compouds by means of a build-in directing group and upon the action of a heteronucleophilic compound (in se an amine (RNH2 or RNHR') or an alcohol (ROH) or a thiol (RSH)) in the presence of a metal catalyst to respectively esters, thioesters, carbonates, thiocarbonates and to what is defined as amide-containing compounds (such as carboxamides, urea, carbamates, thiocarbamates). The present invention also relates to these amide-containing compounds having a build-in directing group (DG), as well as the use of such directing groups in the catalytic directed cleavage of N-DG amides with the use of heteronucleophiles (in se an amine (RNH2 or RNHR') or an alcohol (ROH) or thiol (RSH)).

A new, efficient, and catalyst-free microwave-assisted approach for formation of O-tert-butoxy carbonates

A new simple, efficient, greener, and catalyst-free chemoselective protocol for the O-tert-butoxycarbonylation of various structurally diverse hydroxy compounds was carried out with (Boc)2O under microwave radiation. The corresponding O-tertbutoxy carbonates were obtained in good to excellent yields in a short reaction time without any side reactions.