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A FORMAL STEREOCONTROLLED SYNTHESIS OF (+/-) ISOCLOVENE
Ahmad, Zafeer,Goswami, Pannalal,Venkateswaran, R. V.
, p. 6833 - 6840 (2007/10/02)
Starting from a seven-membered ring compound, the synthesis of the tricyclic ketone (25) is described concluding a formal total synthesis of (+/-) isoclovene, the major sesquiterpene from extensive rearrangement of caryophyllene.Enroute, a facile base pro
