6064-45-5Relevant articles and documents
Polyfunctionalized N-Tensides. VII. Substitution and Elimination in the Reaction of 1,2-Dihalogenoalkanes with Amines
Beger, J.,Meerbote, E.
, p. 12 - 22 (2007/10/02)
1,2-Dichloroalkanes, 1,2-Dibromoalkanes and mixtures of 1-bromo-2-chloroalkanes and 1-chloro-2-bromoalkanes react with primary or secondary amines and give both elimination and substitution products, often in a nearly 1:1 proportion.The elimination products are the cis and trans-1-halo-1-alkenes, the 2-halo-1-alkenes, the 1,3- and 2,4-dienes and the 1-alkenes.The main substitution products are the 1,2-bis-aminoalkanes.Physical dates, 1H-n.m.r.-spectra,surface tension values and CMC-dates are given.