60652-10-0

Basic information

• Product Name: 1-(m-trifluoromethylphenyl)cyclohexene
• Synonyms: 1-(m-trifluoromethylphenyl)cyclohexene
• CAS NO: 60652-10-0
• Molecular Weight: 226.241
• Mol File: 60652-10-0.mol

Chemical Properties

• CAS DataBase Reference: 1-(m-trifluoromethylphenyl)cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(m-trifluoromethylphenyl)cyclohexene(60652-10-0)
• EPA Substance Registry System: 1-(m-trifluoromethylphenyl)cyclohexene(60652-10-0)

Safety Data

• Hazardous Substances Data: 60652-10-0(Hazardous Substances Data)

Upstream product

• 98-17-9 3-Trifluoromethylphenol 
• 199188-30-2 3-(trifluoromethyl)phenyl trifluoromethanesulfonate 
• 110-83-8 cyclohexene 
• 108-94-1 cyclohexanone 
• 402-26-6 3-(trifluoromethyl)phenylmagnesium bromide 
• 401-78-5 3-bromo-1-trifluoromethylbenzene 
• 60652-07-5 1-m-Trifluormethylphenylcyclohexanol 

Downstream Products

• 129353-36-2 1-(3'-Trifluoromethylphenyl)-7-methylenebicyclo<4.1.0>heptane 

Relevant articles and documents

Achieving vinylic selectivity in Mizoroki-heck reaction of cyclic olefins

In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium-hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions. Copyright

Highly selective palladium-catalyzed Heck reactions of aryl bromides with cycloalkenes

Formula presented The influence of palladium catalysts and reaction conditions on the selectivity of Heck reactions of aryl bromides with cyclohexene and cyclopentene has been investigated. It is shown that the addition of DMSO as a cosolvent leads to improved selectivities of nonconjugated aryl olefins. On the other hand, high selectivities for conjugated arylcyclopentenes have been obtained with the catalytic system DMA/Na2-CO3/Pd2(dba) 3·dba/PCy3.