60669-28-5

Basic information

• Product Name: Trifluoromethyliodine(III) bis-trifluoroacetate
• Synonyms: Trifluoromethyliodine(III) bis-trifluoroacetate
• CAS NO: 60669-28-5
• Molecular Weight: 421.943
• Mol File: 60669-28-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Trifluoromethyliodine(III) bis-trifluoroacetate(CAS DataBase Reference)
• NIST Chemistry Reference: Trifluoromethyliodine(III) bis-trifluoroacetate(60669-28-5)
• EPA Substance Registry System: Trifluoromethyliodine(III) bis-trifluoroacetate(60669-28-5)

Safety Data

• Hazardous Substances Data: 60669-28-5(Hazardous Substances Data)

Upstream product

• 812-11-3 trifluoromethyliodine difluoride 
• 350-70-9 tris(trifluoro acetyloxy)borane 
• 14353-86-7 iodine tris(trifluoroacetate) 
• 61110-81-4 dichloro-trifluoromethyl-λ³-iodane 
• 2966-50-9 silver trifluoroacetate 

Downstream Products

• 812-11-3 trifluoromethyliodine difluoride 
• 75-46-7 trifluoromethan 
• 2314-97-8 iodotrifluoromethane 
• 335-05-7 Trifluoromethanesulfonyl fluoride 
• 2024-86-4 trifluoroacetic acid difluoromethyl ester 
• 134365-47-2 Bis-trifluoromethyl-iodonium 
• 56407-84-2 trifluoromethyliodine dioxide 
• 407-25-0 trifluoroacetic anhydride 

Relevant articles and documents

Polar trifluoromethylation reactions: the formation of bis(trifluoromethyl)iodine(III) compounds and trifluoromethyl iodine(III) cations and anions

IX3 (X = Cl, OCOCF3, ONO2) reacts with Cd(CF3)2 complexes or Bi(CF3)3 to yield the corresponding CF3IX2 derivatives. 19F nuclear magnetic resonance spectroscopic evidence is found for + and I(CF3)2X (X = Cl, OCOCF3) in the reactions of CF3IX2 with Cd(CF3)2 complexes.During the reaction of CF3IF2 and Hg(CF3)2 the new species I(CF3)2F and cis-- are identified by nuclear magnetic resonance spectroscopy.The reactions proceed under polar conditions and can be accelerated by the addition of a Lewis acid such as BF3, B(OCOCF3)3, or Sb(V) compounds.Difluoromethyl compounds are formed as by-products.Key words: polar trifluoromethylations, trifluoromethyl iodine(III) compounds, difluoromethyl group formation.