812-11-3

Basic information

• Product Name: trifluoromethyliodine difluoride
• Synonyms: trifluoromethyliodine difluoride
• CAS NO: 812-11-3
• Molecular Weight: 233.908
• Mol File: 812-11-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trifluoromethyliodine difluoride(CAS DataBase Reference)
• NIST Chemistry Reference: trifluoromethyliodine difluoride(812-11-3)
• EPA Substance Registry System: trifluoromethyliodine difluoride(812-11-3)

Safety Data

• Hazardous Substances Data: 812-11-3(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 60669-28-5 Trifluoromethyliodine(III) bis-trifluoroacetate 

Downstream Products

• 75-73-0 carbon tetrafluoride 
• 2314-97-8 iodotrifluoromethane 
• 7553-56-2 iodine 
• 22520-96-3 IF₃ 
• 61110-81-4 dichloro-trifluoromethyl-λ³-iodane 
• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 434-64-0 perfluorotoluene 
• 420-56-4 trimethylsilyl fluoride 
• 60669-28-5 Trifluoromethyliodine(III) bis-trifluoroacetate 
• 38091-67-7 tetrafluoro-trifluoromethyl-λ⁵-iodane 

Relevant articles and documents

Polar trifluoromethylation reactions: the formation of bis(trifluoromethyl)iodine(III) compounds and trifluoromethyl iodine(III) cations and anions

IX3 (X = Cl, OCOCF3, ONO2) reacts with Cd(CF3)2 complexes or Bi(CF3)3 to yield the corresponding CF3IX2 derivatives. 19F nuclear magnetic resonance spectroscopic evidence is found for + and I(CF3)2X (X = Cl, OCOCF3) in the reactions of CF3IX2 with Cd(CF3)2 complexes.During the reaction of CF3IF2 and Hg(CF3)2 the new species I(CF3)2F and cis-- are identified by nuclear magnetic resonance spectroscopy.The reactions proceed under polar conditions and can be accelerated by the addition of a Lewis acid such as BF3, B(OCOCF3)3, or Sb(V) compounds.Difluoromethyl compounds are formed as by-products.Key words: polar trifluoromethylations, trifluoromethyl iodine(III) compounds, difluoromethyl group formation.