6067-21-6

Upstream product

• 67-56-1 methanol 
• 13992-25-1 1-azido-1-deoxy-β-D-glucopyranoside tetraacetate 
• 3947-62-4 2,3,4,6-tetra-O-acetyl-β-D-glucopyranose 
• 67-68-5 dimethyl sulfoxide 
• 186581-53-3 diazomethane 
• 108-24-7 acetic anhydride 
• 90-80-2 D-Glucono-1,5-lactone 
• 61259-48-1 2,3,4,6-tetra-O-acetyl-D-glucono-1,5-lactone 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 136034-24-7 (2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)phenylmethane 
• 1350930-36-7 (2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)(2-nitrophenyl)methane 
• 61259-49-2 2,3,4,6-tetra-O-acetyl-D-gluconic acid 

Relevant academic research and scientific papers

Photochemical conversion of the o-nitrobenzyl-C-glucoside to a sugar lactone

A new family of activated glycosidic compounds has been designed and synthesized: (2,3,4,6-tetra-O-acetyl-β-d-glucopyranosyl)-2- nitrophenylmethane (1). It is stable in conditions commonly used for synthesis, and it can be converted to a sugar lactone der

Syntheses of (3R,4R,5R,6R)-tetrahydroxyazepane (1,6-dideoxy-1,6-imino-D-mannitol) and (3S,4R,5R,6R)-tetrahydroxyazepane (1,6-dideoxy-1,6-imino-D-glucitol)

Syntheses of 1,6-dideoxy-1,6-imino-D-mannitol (D-mannoazepane) (1) and 1,6-dideoxy-1,6-imino-D-glucitol (D-glucoazepane) (3) from D-isoascorbic acid and D-glucono-1,5-lactone, respectively, are described. The key step in both routes involved reductive aminative 1,6-cyclization with retention of configurations to give the corresponding lactams, which were subsequently reduced to afford compounds 1 and 3 in 24 and 28.5%, overall yield, respectively.