60671-14-9Relevant academic research and scientific papers
ALKENE OXIDATION BY AN IRON(II)/PERSULFATE/ACETIC ACID SYSTEM
Fristad, William E.,Peterson, John R.
, p. 1469 - 1476 (2007/10/02)
Mono- and disubstituted alkenes were converted to trans-vicinal diacetates by heating with an iron(II)/persulfate/acetic acid system.The synthetic utility and limitations were identified.A mechanism for the transformation is proposed wich involves an initial addition of sulfate radical anion to the alkene followed by solvolysis, addition, hydrolysis, and acetylation.
IRON(II) CATALYZED ODIDATION OF ALKENES TO VICINAL DIACETATES
Fristad, William E.,Peterson, John R.
, p. 4547 - 4550 (2007/10/02)
Mono- and disubstituted alkenes are converted to trans-vicinal diacetates by heating with an acetic acid solution of ammonium persulfate and a ferrous sulfate catalyst.
The Deoxygenation of NN-Dialkylaminothiocarbonyloxyalkanes
Barrett, Anthony G. M.,Prokopiou, Panayiotis A.,Barton, Derek H. R.
, p. 1510 - 1516 (2007/10/02)
The title compounds were converted into alkanes in high yield on reduction with potassium and 18-crown-6 in t-butylamine.Thereby both primary and secondary alcohols were conveniently deoxygenated.
