606934-96-7Relevant academic research and scientific papers
Hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by zinc/viologen
Zhou, Sheng-Hua,Lin, Jin-Hong,Zhao, Gang,Xiao, Ji-Chang,Cao, Wei-Guo
, p. 60080 - 60083 (2016/07/11)
The hydroperfluoroalkylation of electron-deficient olefins with perfluoroalkyl iodides promoted by a zinc/viologen system is described. Interestingly, no iodoperfluoroalkylation product was observed without the presence of radical H-donor.
Enantiomeric resolution of fluorous mixture by chiral CD columns: Asymmetric reduction of a mixture of fluorous ketones
Nakamura, Yutaka,Takeuchi, Seiji,Okumura, Kazuo,Ohgo, Yoshiaki,Matsuzawa, Hiroshi,Mikami, Koichi
, p. 6221 - 6225 (2007/10/03)
Asymmetric reduction of a mixture of four fluorous ketone analogues was carried out with (R)-oxazaborolidine as a catalyst. The fluorous mixture products were resolved by a reverse phase HPLC with chiral β-cyclodextrin column to result in good separation of the enantiomers.
