607405-07-2

Basic information

• Product Name: methyl (3aS,6aR)-5-[(1R)-1-phenylethyl]tetrahydro-1H-thieno[3,4-c]pyrrole-3a(3H)-carboxylate 2,2-dioxide
• Synonyms: methyl (3aS,6aR)-5-[(1R)-1-phenylethyl]tetrahydro-1H-thieno[3,4-c]pyrrole-3a(3H)-carboxylate 2,2-dioxide
• CAS NO: 607405-07-2
• Molecular Weight: 323.413
• Mol File: 607405-07-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (3aS,6aR)-5-[(1R)-1-phenylethyl]tetrahydro-1H-thieno[3,4-c]pyrrole-3a(3H)-carboxylate 2,2-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (3aS,6aR)-5-[(1R)-1-phenylethyl]tetrahydro-1H-thieno[3,4-c]pyrrole-3a(3H)-carboxylate 2,2-dioxide(607405-07-2)
• EPA Substance Registry System: methyl (3aS,6aR)-5-[(1R)-1-phenylethyl]tetrahydro-1H-thieno[3,4-c]pyrrole-3a(3H)-carboxylate 2,2-dioxide(607405-07-2)

Safety Data

• Hazardous Substances Data: 607405-07-2(Hazardous Substances Data)

Upstream product

• 67488-50-0 methyl 2,5-dihydrothiophene-S,S-dioxide-3-carboxylate 
• 133407-38-2 (R)-N-(1-phenylethyl)-N-(methoxymethyl)-N-(trimethylsilylmethyl)amine 

Downstream Products

• 607405-08-3 [(3aS,6aR)-2,2-dioxido-5-[(1R)-1-phenylethyl]tetrahydro-1H-thieno[3,4-c]pyrrol-3a(3H)-yl]diphenylmethanol 
• 607405-09-4 [(3aS,6aR)-2,2-dioxido-5-[(1R)-1-phenylethyl]tetrahydro-1H-thieno[3,4-c]pyrrol-3a(3H)-yl]bis(4-methoxyphenyl)methanol 
• 607405-10-7 (3aS,6aR)-3a-[(methoxy)diphenylmethyl]-5-[(1R)-1-phenylethyl]hexahydro-1H-thieno[3,4-c]pyrrole 2,2-dioxide 

Relevant articles and documents

Organocatalysts promote enantioselective 1,3-dipolar cycloadditions of nitrones with 1-cycloalkene-1-carboxaldehydes

In the presence of enantiopure organocatalysts, 1-cycloalkene-1-carboxaldehydes and various nitrones furnished fused isoxazolidines. Thus, some chiral pyrrolidinium salts catalyzed the formation of such cycloadducts in high diastereoand enantioselectivity (up to 92% ee). The predominant diastereomer, the exo one, was mostly obtained in excellent diastereoselectivity (> 99:1 dr). Furthermore, after recrystallization of one of the cycloadducts, this was obtained enantiomerically pure (> 99% ee). The absolute configuration of one of the cycloadducts was determined. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.