60754-94-1

Basic information

• Product Name: cis-2-phenyl-1,4-hexadiene
• Synonyms: cis-2-phenyl-1,4-hexadiene
• CAS NO: 60754-94-1
• Molecular Weight: 158.243
• Mol File: 60754-94-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-2-phenyl-1,4-hexadiene(CAS DataBase Reference)
• NIST Chemistry Reference: cis-2-phenyl-1,4-hexadiene(60754-94-1)
• EPA Substance Registry System: cis-2-phenyl-1,4-hexadiene(60754-94-1)

Safety Data

• Hazardous Substances Data: 60754-94-1(Hazardous Substances Data)

Upstream product

• 6738-06-3 phenylethynylmagnesium bromide 
• 4784-77-4 (E/Z)-crotyl bromide 
• 98-81-7 1-bromovinylbenzene 
• 5769-02-8 2-methyl-2-phenyl[1,3]dithiolane 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 4440-01-1 lithium phenylacetylide 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Highly efficient allyl cross-coupling reactions of allylindiums with organic electrophiles

This paper describes highly efficient allyl cross-coupling reactions of allylindiums with organic electrophiles such as aryl and vinyl triflates, vinyl halides, dibromoolefin, and alkynyl iodide. The reactions were carried out using 4 mol % Pd(PPh3)4 in the presence of 3 equiv of LiCl in DMF at 100 °C under a nitrogen atmosphere. Allylindium, generated from the reaction of 1 equiv of indium with 1.5 equiv of allyl halide, gave the best result as a coupling partner. The present method is mild and simple to apply, and it produces a diverse range of allylic compounds in good to excellent yields.