60769-85-9

Basic information

• Product Name: (1S,5R,7R)-3,4-Dioxo-1,7-diphenyl-2-aza-bicyclo[3.2.0]heptane-5-carboxylic acid ethyl ester
• CAS NO: 60769-85-9
• Molecular Weight: 349.386
• Mol File: 60769-85-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1S,5R,7R)-3,4-Dioxo-1,7-diphenyl-2-aza-bicyclo[3.2.0]heptane-5-carboxylic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5R,7R)-3,4-Dioxo-1,7-diphenyl-2-aza-bicyclo[3.2.0]heptane-5-carboxylic acid ethyl ester(60769-85-9)
• EPA Substance Registry System: (1S,5R,7R)-3,4-Dioxo-1,7-diphenyl-2-aza-bicyclo[3.2.0]heptane-5-carboxylic acid ethyl ester(60769-85-9)

Safety Data

• Hazardous Substances Data: 60769-85-9(Hazardous Substances Data)

Upstream product

• 59046-34-3 3-ethoxycarbonyl-2-phenyldioxopyrroline 
• 100-42-5 styrene 
• 60769-85-9 rel-(1S,5R,7R)-5-ethoxycarbonyl-1,7-diphenyl-2-azabicyclo<3.2.0>heptane-3,4-dione 
• 536-74-3 phenylacetylene 
• 122184-91-2 dl.(1R*,5S*)-5-Ethoxycarbonyl-1,7-diphenyl-2-azabicyclo<3.2.0>hept-6-ene-3,4-dione 

Downstream Products

• 60769-85-9 rel-(1S,5R,7S)-5-ethoxycarbonyl-1,7-diphenyl-2-azabicyclo<3.2.0>heptane-2,4-dione 
• 77800-62-5 dl-(1R*,5S*,7S*)-3-ethoxy-5-ethoxycarbonyl-1,7-diphenyl-2-azabicyclo<3.2.0>hept-2-en-4-one 
• 73197-57-6 4-Ethoxycarbonyl-3-hydroxy-6,7-diphenyl-1,5-dihydro-2H-azepin-2-one 
• 99697-85-5 6,7-Diphenyl-4,5-dihydro-1H-azepine-2,3-dione 
• 59046-34-3 3-ethoxycarbonyl-2-phenyldioxopyrroline 
• 66409-59-4 5-ethoxycarbonyl-3,6-diphenyl-3,4-dihydropyridin-2(1H)-one 
• 80016-18-8 2-ethoxy-5-ethoxycarbonyl-3,6-diphenyl-3,4-dihydropyridine 
• 80016-22-4 2-ethoxy-5-ethoxycarbonyl-3,6-diphenylpyridine 
• 67171-72-6 3-Ethoxycarbonyl-2-methoxycarbonyl-5,6-diphenylpyridine 
• 67171-69-1 4-Ethoxycarbonyl-3-methoxy-6,7-diphenyl-2H-azepin-2-one 
• 73197-62-3 4-Ethoxycarbonyl-3-methoxy-6,7-diphenyl-1,5-dihydro-2H-azepin-2-one 
• 67171-74-8 Ethyl 3-ethoxycarbonyl-5,6-diphenylpyridine-2-carboxylate 
• 77800-65-8 7-Ethoxy-5-ethoxycarbonyl-6-hydroxy-2,3-diphenyl-4H-azepine 
• 77800-69-2 2-Ethoxy-4-ethoxycarbonyl-6,7-diphenyl-3H-azepin-3-one 

Relevant articles and documents

Dioxopyrrolines. XLIX. Synthesis of azatropolones via photocycloaddition of 5-aryl-4-ethoxycarbonyl-1H-pyrrole-2,3-diones to acetylenes and ethylenes

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2-AZABICYCLOHEPTANE-3,4-DIONES (2): STEREOCHEMISTRY OF THE PHOTO-CYCLOADDUCTS OF 3-ETHOXYCARBONYL-2-PHENYL-Δ2-PYRROLINE-4,5-DIONE WITH SUBSTITUTED OLEFINS.

The stereochemistries of photo-cycloadducts of 3-ethoxycarbonyl-2-phenyl-Δ2-pyrroline-4,5-dione with substituted olefins were established by chemical and spectroscopic means.Styrene- and butadiene-major adducts were 7-exo-isomers, while ethyl vinyl ether- and vinyl acetate-major adducts were 7-endo-isomers.The 7,7'-disubstitutsd derivative, the isopropenyl acetate-adduct, was also established as an O-endo-isomer.