607715-90-2

Upstream product

• 97321-70-5 2,6-anhydro-3,4,5,7-tetra-O-benzyl-1-deoxy-β-D-manno-hept-1-enitol 
• 82598-88-7 2,3,4,6-tetra-O-benzyl-D-mannono-1,5-lactone 

Downstream Products

• 1234178-35-8 C₄₇H₅₆O₅ 
• 1234178-32-5 C₄₃H₄₀O₅ 
• 1234178-33-6 C₄₀H₄₄O₅Si 

Relevant academic research and scientific papers

Sonogashira couplings of halo- and epoxy-halo-exo-glycals: Concise entry to carbohydrate-derived enynes

Furanose- and pyranose-derived mono- and dihalo-exo-glycals undergo Sonogashira coupling reactions in the presence of Pd catalysts to give carbohydrate-derived enynes in a completely stereoselective manner. On the other hand, a furanose-derived 2, 3-anhydrohalo-exo-glycal, available from D-mannose in five steps, undergoes Pd0-catalyzed Sonogashira coupling, leading to 2-deoxyenynes.

Stereoselective synthesis of substituted exo-glycals from 1-exo-methylene pyranoses

Halo-exo-glycals of the gluco-, manno- and galacto- series, readily prepared by reaction of 1-exo-methylene pyranoses with iodonium dicollidinium triflate (IDCT), undergo Suzuki or B-alkyl Suzuki cross-coupling reactions with boronic acids or alkyl borane