60779-09-1

Basic information

• Product Name: 1-phenylethylmagnesium chloride
• Synonyms: 1-phenylethylmagnesium chloride
• CAS NO: 60779-09-1
• Molecular Weight: 164.917
• Mol File: 60779-09-1.mol

Chemical Properties

• CAS DataBase Reference: 1-phenylethylmagnesium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylethylmagnesium chloride(60779-09-1)
• EPA Substance Registry System: 1-phenylethylmagnesium chloride(60779-09-1)

Safety Data

• Hazardous Substances Data: 60779-09-1(Hazardous Substances Data)

Upstream product

• 672-65-1 (1-chloroethyl)benzene 
• 98-85-1 1-Phenylethanol 

Downstream Products

• 10340-49-5 4-phenyl-1-pentene 
• 84519-64-2 (R)-(E)-4-phenyl-2-pentene 
• 96391-87-6 (S)-(E)-4-phenyl-2-pentene 
• 53172-83-1 2-methyl-3-phenyl-1-butene 
• 7302-01-4 (Z)-(3-methyl-1-propene-1,3-diyl)dibenzene 
• 642093-53-6 (S,E)-1-methyl-4-(3-phenylbut-1-en-1-yl)benzene 
• 643726-36-7 (R)-(anti,syn)-N-α-methylbenzylbis(α-methylbenzyl)phosphinic amide 
• 24422-69-3 (1-phenylethyl)(4-methylphenyl)sulfide 
• 7100-97-2 1-fluoro-1-phenylethane 
• 107771-41-5 ethyl 5-phenylhexanoate 
• 884050-47-9 [Cy-N=C(para-fluorophenyl)-C(para-fluorophenyl)=N-Cy]FeCl₂ 
• 110551-83-2 [(N,N'dicyclohexylethanediimine)FeCl₂] 

Relevant articles and documents

Asymmetric Grignard cross-coupling reaction: An investigation of the factors influencing asymmetric induction with a new type of pyrrolidinephosphane

An investigation of the asymmetric synthesis of 3-phenyl-lbutene by the Grignard cross-coupling reaction is presented. The reaction is catalysed by nickel complexes of bisphosphane and 3-diphenylphosphanylpyrrolidine-type ligands. A comparison of the resu

Mechanical Activation of Magnesium Turnings for the Preparation of Reactive Grignard Reagents

Preactivation of magnesium by dry stirring in an inert atmosphere is highly beneficial for the clean synthesis of reactive allylic or benzylic organomagnesium chlorides.This procedure routinely produces 0.4 M solutions of the Grignard reagent in diethyl ether free from coupling products.The purity may be directly assayed by 13C spectroscopy.Using spin saturation transfer techniques, the rate constant for interconversion of the enantiomers of (1-phenyl-2-methylpropyl)magnesium chloride in Et2O at 25 deg C was shown to be -1.Electron microscopy has been used to define the surface changes occurring during the dry stirring of magnesium turnings.