110551-83-2

Basic information

• Product Name: [(N,N'dicyclohexylethanediimine)FeCl₂]
• Synonyms: [(N,N'dicyclohexylethanediimine)FeCl₂]
• CAS NO: 110551-83-2
• Molecular Weight: 347.111
• Mol File: 110551-83-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: [(N,N'dicyclohexylethanediimine)FeCl₂](CAS DataBase Reference)
• NIST Chemistry Reference: [(N,N'dicyclohexylethanediimine)FeCl₂](110551-83-2)
• EPA Substance Registry System: [(N,N'dicyclohexylethanediimine)FeCl₂](110551-83-2)

Safety Data

• Hazardous Substances Data: 110551-83-2(Hazardous Substances Data)

Upstream product

• 474396-91-3 (iron(III))(trichloride)(N₂C₂H₂)(cyclohexyl)2 
• 60779-09-1 1-phenylethylmagnesium chloride 
• 6921-34-2 benzylmagnesium chloride 
• 62801-14-3 bis[glyoxalbis(cyclohexylimine)]iron 
• 2696-92-6 nitrosylchloride 
• 21475-90-1 cis-[Fe(CO)4Cl₂] 

Downstream Products

• 1313239-78-9 [1,4-dicyclohexyl-1,4-diazabuta-1,3-diene]Fe(iodide)2(carbonyl)2 
• 1313239-77-8 [1,4-dicyclohexyl-1,4-diazabuta-1,3-diene]Fe(iodide)2 

Relevant articles and documents

METHOD OF PRODUCING ORGANIC SILICON COMPOUND

PROBLEM TO BE SOLVED: To provide a method of producing an organic silicon compound efficiently by improving a catalyst for hydrosilylation reactions of alkenes and alkynes. SOLUTION: An organic silicon compound can be produced efficiently by using an iron

Organometallic intermediates in the controlled radical polymerization of styrene by α-diimine iron catalysts

The α-diimine iron complexes R′,R″[N,N] FeCl2 (R′,R″[N,N] = R′-N=CR″- CR =N-R′) are efficient catalysts for the atom-transfer radical polymerization (ATRP) of styrene when R′ and R″ are electrondonating substituents and favor catalytic chain transfer (CCT) when electron-withdrawing substituents are employed. An organometallic pathway, alongside a halogen-atom-transfer equilibrium, is proposed to mediate the observed reactivity. The model alkyl complexes, R′,R″[N,N] FeCl2(R), where R = PhCH2 and Ph(Me)CH, were generated via treatment of R′,R″[N, N]FeCl3 with RMgCl. The alkyl derivatives obtained from intermediate spin-state R′,R″[N,N]FeCl3 complexes were found to be stable to ca. -30 °C and favor CCT, whereas the alkyl derivatives derived from high-spin-state trichloride precursors are unstable above -78 °C and favor ATRP. Azo-initiated polymerizations of styrene are moderately controlled by a-diimine iron catalysts. The role of organometallic-mediated radical polymerization (OMRP) in the controlled polymerization of styrene is discussed: an analysis of the radical concentrations generated by the competing OMRP and ATRP equilibria indicates that the halogenophilicity of the Fe(II) catalyst dominates the carbophilic alkyl radical-trapping capacity of the Fe(II) species in this a-diimine catalyst system.

Four-coordinate iron complexes bearing α-diimine ligands: Efficient catalysts for Atom Transfer Radical Polymerisation (ATRP)

Four-coordinate iron(II) complexes bearing α-diimine ligands with alkyl substituents are shown to be efficient catalysts for the well-controlled atom transfer radical polymerisation of styrene; catalysts containing aryldiimine ligands support competitive