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6079-76-1

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6079-76-1 Usage

Preparation

Preparation by reaction of benzyl chloride with 2,4-dihydroxybenzophenone (resbenzophenone), ? in the presence of potassium carbonate in refluxing acetone; ? in the presence of potassium carbonate and potassium iodide in N,Ndimethylformamide at 100° for 1.5 h (95%).

Check Digit Verification of cas no

The CAS Registry Mumber 6079-76-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,0,7 and 9 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 6079-76:
(6*6)+(5*0)+(4*7)+(3*9)+(2*7)+(1*6)=111
111 % 10 = 1
So 6079-76-1 is a valid CAS Registry Number.
InChI:InChI=1/C20H16O3/c21-19-13-17(23-14-15-7-3-1-4-8-15)11-12-18(19)20(22)16-9-5-2-6-10-16/h1-13,21H,14H2

6079-76-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name (2-hydroxy-4-phenylmethoxyphenyl)-phenylmethanone

1.2 Other means of identification

Product number -
Other names 2-Hydroxy-4-benzyloxybenzophenon

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6079-76-1 SDS

6079-76-1Downstream Products

6079-76-1Relevant articles and documents

A dehydrative arylation and thiolation of tertiary alcohols catalyzed by in situ generated triflic acid - Viable protocol for C–C and C–S bond formation

Roy, Deblina,Panda, Gautam

, p. 6270 - 6277 (2018)

The title paper discusses a mild strategy for an efficient C–C and C–S bond formation through ortho-quinone methide intermediate. A total of 29 examples (23 tetrasubstituted methanes with a quaternary carbon center and 6 triarylmethyl thioarenes) with diverse substitution patterns could be prepared in high yields (up to 82%). Use of indium triflate allowed the transformation to be carried out in an open flask without taking special care leaving water as the only by product. Control experiments revealed that the triflic acid generated in situ from indium triflate, probably through the coordination with substrate, acted as the actual catalyst for the transformation. Further this protocol can be utilized for the synthesis of promising bioactives such as CDRI-830 analogues, dihydrochromeno[2,3-b]indoles and 9-(1H-indol-3-yl)-9-phenyl-9H-xanthen-1-ol.

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