60841-82-9Relevant academic research and scientific papers
Synthesis and characterization of metal-β-diketonate coordination complexes and polymers
Al-Anber, Mohammed A.,Daoud, Hannen
, p. 905 - 909 (2014/03/21)
A mononuclear [M(tba)2(H2O)2] (3: M = Mn, 4: M = Ni, 5: M = Zn; tba = deprotonated of 1) complexes have been prepared by the reaction of 3-benzoyl-1 .1.1 -trifluoro-acetone (H-tba: 1) with M(OAc) 2.nH2O (M = Mn, Ni, Zn; OAc = O2CMe) in a 2:1 molar ratio. Complexes 3 - 5 can be extended to form a coordination polymers of general tormula [M(tba)2(4,4'-bipy)]5 (6: M = Mn, 7: M = Ni, 8: M = Zn; tba = 3-benzoyl-I.I.I-trifluoro-acetone; 4,4-bipy = 4,4'-bipyridine) by bridging the central metal atom with 4,4'-bipyridine (4,4-bipy). The reaction progress was controlled via FTIR, UV-Vis spectroscopy and elemental analysis.
