60848-13-7

Upstream product

• 2216-94-6 phenylpropynoic acid ethyl ester 
• 247926-43-8 10-(dimethylamino)-1-iodophenanthrene 
• 66087-65-8 N, 2'-dimethyl-[1,1'-biphenyl]-2-carboxamide 
• 7111-77-5 2'-methyl[1,1'-biphenyl]-carboxylic acid 
• 188943-06-8 methyl 2'-methyl-[1,1'-biphenyl]-2-carboxylate 

Relevant academic research and scientific papers

Amide-Directed C?H Sodiation by a Sodium Hydride/Iodide Composite

A new protocol for amide-directed ortho and lateral C?H sodiation is enabled by sodium hydride (NaH) in the presence of either sodium iodide (NaI) or lithium iodide (LiI). The transient organosodium intermediates could be transformed into functionalized aromatic compounds.

Palladium-catalysed synthesis of dibenzo[de,g]quinolines. A novel approach to the B-ring system of aporphine-related heterocycles

Dibenzo[de,g]quinolines 5 were formed by the palladium-catalysed heteroannulation of disubstituted alkynes and 1-iodo-10- (dimethylamino)phenanthrene (3c). Symmetric alkynes led to high levels of regioselectivity. These reactions constitute a new synthesis of the B-ring system of aporphine heterocycles.