6093-01-2

Basic information

• Product Name: [4-(2-[4-(aminomethyl)phenyl]-6-{[2-(methoxymethyl)pyrrolidin-1-yl]methyl}-1,3-dioxan-4-yl)phenyl]methanol
• CAS NO: 6093-01-2
• Molecular Formula: C₂₂H₂₂
• Molecular Weight: 426.5485
• Mol File: 6093-01-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 600.8°C at 760 mmHg
• Flash Point: 317.1°C
• Density: 1.158g/cm³
• Vapor Pressure: 2.77E-15mmHg at 25°C
• Refractive Index: 1.572
• CAS DataBase Reference: [4-(2-[4-(aminomethyl)phenyl]-6-{[2-(methoxymethyl)pyrrolidin-1-yl]methyl}-1,3-dioxan-4-yl)phenyl]methanol(CAS DataBase Reference)
• NIST Chemistry Reference: [4-(2-[4-(aminomethyl)phenyl]-6-{[2-(methoxymethyl)pyrrolidin-1-yl]methyl}-1,3-dioxan-4-yl)phenyl]methanol(6093-01-2)
• EPA Substance Registry System: [4-(2-[4-(aminomethyl)phenyl]-6-{[2-(methoxymethyl)pyrrolidin-1-yl]methyl}-1,3-dioxan-4-yl)phenyl]methanol(6093-01-2)

Safety Data

• Hazardous Substances Data: 6093-01-2(Hazardous Substances Data)

Upstream product

• 98-82-8 Isopropylbenzene 
• 908093-98-1 diazodiphenylmethane 
• 41976-80-1 (2-methoxyethane-1,1-diyl)dibenzene 
• 1871-57-4 2-chloromethyl-3-chloroprop-1-ene 
• 71-43-2 benzene 
• 934-53-2 cumenyl chloride 
• 101-81-5 Diphenylmethane 

Downstream Products

• 109704-59-8 exo-2-(diphenylmethyl)-2-methoxynorbornane 
• 109704-63-4 exo-2-(diphenylmethyl)-2-hydroxynorbornane 
• 935-67-1 Cumyl methyl ether 
• 101-81-5 Diphenylmethane 

Relevant articles and documents

Triplet halocarbene chemistry: P-nitrophenylchlorocarbene and p-nitrophenylbromocarbene

Reactions of p-nitrophenylchlorocarbene with cumene and of p-nitrophenylbromocarbene with toluene afford C-H abstraction-recombination products that suggest the involvement of triplet arylhalocarbenes.

Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl)carbenes: Isolation, X-ray crystal structures, and carbon atom transfer reactions with hydrocarbons

Reactions of [Fe(TPFPP)] (TPFPP = meso-tetrakis(pentafluorophenyl)porphyrinato dianion) with diazo compounds N2C(Ph)R (R = Ph, CO2Et, CO2CH2CH=CH2) afforded [Fe(TPFPP)(C(Ph)R)] (R = Ph (1), CO2Et (2), CO2CH2CH=CH2 (3)) in 65-70% yields. Treatment of 1 with N-methylimidazole (Melm) gave the adduct [Fe(TPFPP)(CPh2)(Melm)] (4) in 65% yield. These new iron porphyrin carbene complexes were characterized by NMR and UV-vis spectroscopy, mass spectrometry, and elemental analyses. X-ray crystal structure determinations of 1·0.5C6H6·0.5CH2Cl2 and 4 reveal Fe=CPh2 bond lengths of 1.767(3) (1) and 1.827(5) A (4), together with large ruffling distortions of the TPFPP macrocycle. Complexes 2 and 4 are reactive toward styrene, affording the corresponding cyclopropanes in 82 and 53% yields, respectively. Complex 1 is an active catalyst for both intermolecular cyclopropanation of styrenes with ethyl diazoacetate and intramolecular cyclopropanation of allylic diazoacetates. Reactions of 2 and 4 with cyclohexene or cumene produced allylic or benzylic C-H insertion products in up to 83% yield.