609347-86-6

Basic information

• Product Name: L-Phenylalanine, N-[(1,1-dimethylethoxy)carbonyl]glycyl-N-[[(2,4-dimethoxyphenyl)dimeth ylsilyl]methyl]-, methyl ester
• CAS NO: 609347-86-6
• Molecular Formula: C28H40N2O7Si
• Molecular Weight: 544.72
• Mol File: 609347-86-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: L-Phenylalanine, N-[(1,1-dimethylethoxy)carbonyl]glycyl-N-[[(2,4-dimethoxyphenyl)dimeth ylsilyl]methyl]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: L-Phenylalanine, N-[(1,1-dimethylethoxy)carbonyl]glycyl-N-[[(2,4-dimethoxyphenyl)dimeth ylsilyl]methyl]-, methyl ester(609347-86-6)
• EPA Substance Registry System: L-Phenylalanine, N-[(1,1-dimethylethoxy)carbonyl]glycyl-N-[[(2,4-dimethoxyphenyl)dimeth ylsilyl]methyl]-, methyl ester(609347-86-6)

Safety Data

• Hazardous Substances Data: 609347-86-6(Hazardous Substances Data)

Upstream product

• 4530-20-5 BOC-glycine 
• 609347-83-3 2-({[(2,4-dimethoxyphenyl)dimethylphenylsilanyl]methyl}amino)-3-phenylpropionic acid methyl ester 
• 7524-50-7 methyl (2S)-2-amino-3-phenylpropanoate hydrochloride 
• 609347-79-7 (chloromethyl)dimethyl(2,4-dimethoxyphenyl)silane 
• 17715-69-4 1-Bromo-2,4-dimethoxybenzene 
• 66866-43-1 N-(t-butoxycarbonyl)glycyl i-butyl carbonate 

Relevant articles and documents

Building functionalized peptidomimetics: Use of electroauxiliaries for introducing N-acyliminium ions into peptides

A series of silyl-substituted amino acids have been synthesized, inserted into peptides, and then employed as precursors for oxidatively generating reactive N-acyliminium ions. Both electrochemical and chemical oxidation procedures have been employed. N-Acyliminium ion generation in a solid-phase substrate as well as application to a small library of functionalized dipeptides has been demonstrated. Limitations in terms of how electron-rich the silyl groups can be as well as the compatibility of multiple silyl groups within a longer peptide are defined.