61007-43-0Relevant academic research and scientific papers
B(C6F5)3-Catalyzed Michael Reactions: Aromatic C-H as Nucleophiles
Li, Wu,Werner, Thomas
, p. 2568 - 2571 (2017)
The Michael reaction is a widely used reaction for the C-C coupling of electron-poor olefins and C(sp3)-H pronucleophiles. Herein we report the Michael reaction between alkenes and aromatic as well as heteroaromatic compounds as aromatic C(sps
Michael Additions Catalyzed by a β-Diketiminate-Supported Aluminum Complex
Liu, Zhizhou,Vidovi?, Dragoslav
, p. 5295 - 5300 (2018/05/15)
A β-diketiminate-supported aluminum bistriflate complex (DipLAl(OTf)2·Na[BArCl4]; DipL = CH(CMe)2(N-C6H3-iPr2)2; Tf = O2SCF
Gold-catalyzed hydroarylation of alkenes with dialkylanilines
Hu, Xingbang,Martin, David,Melaimi, Mohand,Bertrand, Guy
supporting information, p. 13594 - 13597 (2015/02/05)
Anti-Bredt di(amino)carbene supported gold(I) chloride complexes are readily prepared in two steps from the corresponding isocyanide complexes. In the presence of KB(C6F5)4as chloride scavenger, they promote the unprecedented hydroarylation reaction of alkenes with N,N-dialkylanilines with high para-selectivity. The latter are challenging arenes for Friedel-Craft reactions, due to their high basicity.
