61040-96-8Relevant articles and documents
Regioselective Hydroperoxylation of Aziridines and Epoxides Only with Aqueous Hydrogen Peroxide
Saleh, SK Abu,Hazra, Atanu,Hajra, Saumen
, p. 391 - 404 (2021/11/01)
A catalyst and organic solvent-free regioselective hydroperoxylation of aziridines and epoxides, including spiroaziridine- and spiroepoxy oxindoles have been explored with commercially available 50% aq. H2O2. This method provides an access to secondary benzylic β-hydroperoxy amines and -alcohols and tertiary 3-hydroperoxy oxindoles. The protocol is also applicable to the less reactive alkyl aziridines. Furthermore, an acid-catalyzed Kornblum-DeLaMare type rearrangement of secondary benzylic hydroperoxide has also been revealed to afford amino- and hydroxyl ketones. (Figure presented.).
Magnetic nano-graphene oxide-supported molybdenum (Fe3O4/GO-Mo) as a green, efficient, and recyclable catalyst for synthesis of β-hydroxy hydroperoxides
Liu, Yu-Heng,Hu, Hai-Chuan,Ma, Zi-Chuan,Dong, Yan-Fei,Wang, Can,Pang, Yun-Meng
, p. 551 - 556 (2018/03/27)
Abstract: Magnetic nano-graphene oxide-supported molybdenum was readily prepared and identified as an efficient and recyclable catalyst for ring opening of various epoxides with ethereal hydrogen peroxide. The reaction proceeded under mild conditions to g
Efficient conversion of epoxides into β-hydroperoxy alcohols catalyzed by antimony trichloride/SiO2
Liu, Yu-Heng,Zhang, Zhan-Hui,Li, Tong-Shuang
experimental part, p. 3314 - 3318 (2009/05/07)
Efficient ring-opening of various epoxides with hydrogen peroxide, catalyzed by antimony trichloride/SiO2, afforded the corresponding β-hydroperoxy alcohols in good to excellent yields under mild reaction conditions. The reactions were efficien