610778-27-3Relevant academic research and scientific papers
A general, regiospecific synthetic route to perfluoroalkylated arenes via arenediazonium salts with RFCu(CH3CN) complexes
Jiang, Dong-Fang,Liu, Chao,Guo, Yong,Xiao, Ji-Chang,Chen, Qing-Yun
supporting information, p. 6303 - 6309 (2015/03/30)
A mild method of converting arylamines into perfluoroalkylated arenes is described. Relatively stable RFCu(CH3CN) complexes are used as perfluoroalkylating agents, which react smoothly with arenediazonium salts to produce various perfluoroalkylarenes in good yields. Based on the results of clock trapping experiments with diallyl ether, a radical process might be involved in the reaction.
Calamitic bolaamphiphiles with (semi)perfluorinated lateral chains: Polyphilic block molecules with new liquid crystalline phase structures
Cheng, Xiaohong,Prehm, Marko,Das, Malay Kumar,Kain, Jens,Baumeister, Ute,Diele, Siegmar,Leine, Dag,Blume, Alfred,Tschierske, Carsten
, p. 10977 - 10996 (2007/10/03)
Novel bolaamphiphiles consisting of a rigid biphenyl unit, two terminal polar 1,2-diol units and laterally attached (semi)perfluorinated chains have been synthesized via palladium-catalyzed cross coupling reactions as the key step. The thermotropic liquid
