61080-12-4

Basic information

• Product Name: Benzene, 1,1'-(phenylethenylidene)bis[4-methyl-
• CAS NO: 61080-12-4
• Molecular Formula: C22H20
• Molecular Weight: 284.401
• Mol File: 61080-12-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(phenylethenylidene)bis[4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(phenylethenylidene)bis[4-methyl-(61080-12-4)
• EPA Substance Registry System: Benzene, 1,1'-(phenylethenylidene)bis[4-methyl-(61080-12-4)

Safety Data

• Hazardous Substances Data: 61080-12-4(Hazardous Substances Data)

Upstream product

• 7436-90-0 2,2-dibromostyrene 
• 5720-05-8 4-methylphenylboronic acid 
• 536-74-3 phenylacetylene 
• 150177-33-6 (Z)-(1-phenylethene-1,2-diyl)bis(trimethylgermane) 
• 624-31-7 4-tolyl iodide 
• 83947-56-2 4,4,5,5-tetramethyl-2-((E)-styryl)-[1,3,2]dioxaborolane 
• 122-78-1 phenylacetaldehyde 
• 60-12-8 2-phenylethanol 
• 74213-48-2 4,4,5,5-tetramethyl-2-[(1Z)-2-phenylethenyl]-1,3,2-dioxaborolane 
• 1566-67-2 (Z)-styryl acetate 
• 1566-65-0 cinnamylacetate 
• 100-39-0 benzyl bromide 
• 74-88-4 methyl iodide 
• 611-97-2 bis(p-methylphenyl)-methanone 

Downstream Products

• 857787-10-1 2,2-bis(4-methylphenyl)-1-phenylvinyl bromide 
• 860582-67-8 2-phenyl-3,3-di-p-tolyl-acrylic acid 
• 10421-90-6 6-methyl-2-phenyl-3-p-tolyl-inden-1-one 

Relevant articles and documents

Synthesis of vinylgermanes via the Au/TiO2-catalyzed cis-1,2-digermylation of alkynes and the regioselective hydrogermylation of allenes

In the presence of Au/TiO2 (1 mol %), terminal alkynes react quantitatively with stoichiometric amounts of the unactivated digermane Me3Ge-GeMe3, forming exclusively cis-1,2-digermylated alkenes. We also establish the Au/TiO2-catalyzed hydrogermylation of terminal allenes with Et3GeH, which exhibits a highly regioselective mode of addition on the more substituted double bond forming vinylgermanes. Additionally, we provide preliminary results regarding the Pd nanoparticle-catalyzed C-C coupling of 1,2-digermyl alkenes with aryl iodides.

Effective palladium-catalyzed synthesis of triarylethene-based molecules in aqueous solution

Highly effective and selective Pd-catalyzed coupling reactions of 1,1-dibromo-1-alkenes with various arylboronic acids have been performed in aqueous solution under mild conditions. The method is simple, economic, and practical for the synthesis of triarylethene-based compounds. Copyright

Pd-catalyzed C=C double-bond formation by coupling of N-tosylhydrazones with benzyl halides

Pd-catalyzed reaction of N-tosylhydrazones with benzyl halides affords di- and trisubstituted olefins In high yields with excellent stereoselectivity. This coupling reaction Is supposed to proceed through a migratory insertion of Pd carbene species.