611236-27-2

Upstream product

• 2100-17-6 4-pentenal 
• 327628-32-0 [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocamphenylborane 
• 18001-18-8 allyldimethylphenylsilane 

Downstream Products

• 611236-30-7 (3S,4R)-3-dimethylphenylsilyl-octa-1,7-dien-4-yl t-butyldimethylsilyl ether 
• 611236-33-0 (1R,2S)-2-(dimethylphenylsilanyl)-cyclohex-3-enyl t-butyldimethylsilyl ester 
• 757749-27-2 (1R,2R,3R,4R)-2-dimethylphenylsilylcyclohexa-1,3,4-triol 
• 757748-86-0 acetic acid 2-(dimethylphenylsilanyl)-cyclohex-3-enyl ester 
• 757748-20-2 (1R,2S)-2-(dimethylphenylsilanyl)-cyclohex-3-enol 

Relevant academic research and scientific papers

Highly diastereoselective electrophilic fluorination of cyclic syn-β-hydroxysilanes

A synthesis of enantioenriched fluorinated carbocycles has been developed combining a sequential enantioselective silylallylboration-ring-closing metathesis with a highly diastereoselective electrophilic fluorination. Georg Thieme Verlag Stuttgart.

Asymmetric synthesis of cyclic β-hydroxyallylsilanes via sequential allyltitanation-ring closing metathesis

Highly enantioenriched cyclic β-hydroxyallylsilanes have been prepared via enantioselective allylation of unsaturated aldehydes using a chiral allyltitanium reagent, followed by a ring-closing metathesis. Functionalized rings of various sizes have been sy

Enantio- and diastereoselective synthesis of cyclic β-hydroxy allylsilanes via sequential aldehyde γ-silylallylboration and ring-closing metathesis reactions

(Matrix presented) Highly enantioenriched cyclic allylsilanes are prepared via stereoselective γ-silylallylboration reactions of β- or γ-unsaturated aldehydes followed by ring-closing metathesis.