612819-96-2

Basic information

• Product Name: (3S,7S,8R,9S)-3-(tert-butyldiphenylsilanyloxymethyl)-7,8-oxahexahydroindolizin-5-one
• Synonyms: (3S,7S,8R,9S)-3-(tert-butyldiphenylsilanyloxymethyl)-7,8-oxahexahydroindolizin-5-one
• CAS NO: 612819-96-2
• Molecular Weight: 421.612
• Mol File: 612819-96-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,7S,8R,9S)-3-(tert-butyldiphenylsilanyloxymethyl)-7,8-oxahexahydroindolizin-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,7S,8R,9S)-3-(tert-butyldiphenylsilanyloxymethyl)-7,8-oxahexahydroindolizin-5-one(612819-96-2)
• EPA Substance Registry System: (3S,7S,8R,9S)-3-(tert-butyldiphenylsilanyloxymethyl)-7,8-oxahexahydroindolizin-5-one(612819-96-2)

Safety Data

• Hazardous Substances Data: 612819-96-2(Hazardous Substances Data)

Upstream product

• 138629-30-8 (S)-tert-butyl 2-((tert-butyldiphenylsilyloxy)methyl)-5-oxopyrrolidine-1-carboxylate 
• 161424-44-8 <2S-trans-(Z)>-5-Propenyl-1,2-pyrrolidinedicarboxylic acid 1-(1,1-dimethylethyl) 2-methyl diester 
• 192389-43-8 (5S)-1-(benzyloxycarbonyl)-5-[(tert-butyldiphenylsilyl)oxymethyl]-2-hydroxypyrrolidine 
• 612819-94-0 (3S,9S)-3-(tert-butyldiphenylsilanyloxymethyl)-2,3,6,8a-tetrahydro-1H-indolizin-5-one 
• 612820-28-7 (2S,5S)-2-(tert-butyldiphenylsilanyloxymethyl)-5-propenylpyrrolidine-1-carboxylic acid tert-butyl ester 
• 612819-91-7 (3S,9S)-5-oxo-1,2,3,5,6,8a-hexahydroindolizine-3-carboxylic acid 
• 612819-90-6 (3S,9S)-5-oxo-1,2,3,5,6,8a-hexahydroindolizine-3-carboxylic acid methyl ester 
• 612819-89-3 (2S,5S)-1-but-3-enoyl-5-cis-propenylpyrrolidine-2-carboxylic acid methyl ester 

Downstream Products

• 181705-72-6 (3S,8S,9R)-3-(tert-butyldiphenylsilanyloxymethyl)-8-hydroxyhexahydroindolizin-5-one 
• 743423-44-1 (3S,8S,9R)-3-(tert-butyldiphenylsilanyloxymethyl)-8-methoxyhexahydroindolizin-5-one 

Relevant articles and documents

Synthesis of diversely functionalized indolizidinones and related bicyclic lactams using intramolecular Grubbs olefin metathesis and Dieckmann condensation

Bicyclic 1-aza-2-oxo ring systems with versatile functionality were synthesized from the Grubbs olefin metathesis of appropriate olefinic precursors, starting with L-pyroglutamic acid. The carbocyclization products were further functionalized utilizing th