743423-44-1

Basic information

• Product Name: (3S,8S,9R)-3-(tert-butyldiphenylsilanyloxymethyl)-8-methoxyhexahydroindolizin-5-one
• Synonyms: (3S,8S,9R)-3-(tert-butyldiphenylsilanyloxymethyl)-8-methoxyhexahydroindolizin-5-one
• CAS NO: 743423-44-1
• Molecular Weight: 437.654
• Mol File: 743423-44-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3S,8S,9R)-3-(tert-butyldiphenylsilanyloxymethyl)-8-methoxyhexahydroindolizin-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,8S,9R)-3-(tert-butyldiphenylsilanyloxymethyl)-8-methoxyhexahydroindolizin-5-one(743423-44-1)
• EPA Substance Registry System: (3S,8S,9R)-3-(tert-butyldiphenylsilanyloxymethyl)-8-methoxyhexahydroindolizin-5-one(743423-44-1)

Safety Data

• Hazardous Substances Data: 743423-44-1(Hazardous Substances Data)

Upstream product

• 181705-84-0 2-(tert-butyl-diphenyl-silanyloxymethyl)-5-(5-oxo-tetrahydro-furan-2-yl)-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 181705-70-4 (5S,2'S,5'S)-5-[1'-(tert-butoxycarbonyl)-5'-(tert-butyldiphenylsilyloxymethyl)pyrrolidin-2'-yl]-2(5H)-furanone 
• 181705-71-5 (5S,2'S,5'S)-5-[5'-(tert-butyldiphenylsilyloxymethyl)pyrrolidin-2'yl]-tetrahydrofuran-2-one 
• 138629-30-8 (S)-tert-butyl 2-((tert-butyldiphenylsilyloxy)methyl)-5-oxopyrrolidine-1-carboxylate 
• 181705-72-6 (3S,8S,9R)-3-(tert-butyldiphenylsilanyloxymethyl)-8-hydroxyhexahydroindolizin-5-one 
• 74-88-4 methyl iodide 
• 612819-96-2 (3S,7S,8R,9S)-3-(tert-butyldiphenylsilanyloxymethyl)-7,8-oxahexahydroindolizin-5-one 
• 612820-28-7 (2S,5S)-2-(tert-butyldiphenylsilanyloxymethyl)-5-propenylpyrrolidine-1-carboxylic acid tert-butyl ester 
• 612819-94-0 (3S,9S)-3-(tert-butyldiphenylsilanyloxymethyl)-2,3,6,8a-tetrahydro-1H-indolizin-5-one 
• 612819-89-3 (2S,5S)-1-but-3-enoyl-5-cis-propenylpyrrolidine-2-carboxylic acid methyl ester 
• 612819-91-7 (3S,9S)-5-oxo-1,2,3,5,6,8a-hexahydroindolizine-3-carboxylic acid 
• 612819-90-6 (3S,9S)-5-oxo-1,2,3,5,6,8a-hexahydroindolizine-3-carboxylic acid methyl ester 
• 161424-44-8 <2S-trans-(Z)>-5-Propenyl-1,2-pyrrolidinedicarboxylic acid 1-(1,1-dimethylethyl) 2-methyl diester 
• 192389-43-8 (5S)-1-(benzyloxycarbonyl)-5-[(tert-butyldiphenylsilyl)oxymethyl]-2-hydroxypyrrolidine 

Downstream Products

• 267661-37-0 Acetic acid (3S,6S,8S,8aS)-3-(4-{amino-[(Z)-benzyloxycarbonylimino]-methyl}-benzylcarbamoyl)-6-benzyl-8-methoxy-5-oxo-octahydro-indolizin-6-yl ester 
• 267661-38-1 [1-Amino-1-(4-{[((3S,6S,8S,8aS)-6-benzyl-6-hydroxy-8-methoxy-5-oxo-octahydro-indolizine-3-carbonyl)-amino]-methyl}-phenyl)-meth-(Z)-ylidene]-carbamic acid benzyl ester 
• 267661-36-9 (3S,6S,8S,8aS)-6-Acetoxy-6-benzyl-8-methoxy-5-oxo-octahydro-indolizine-3-carboxylic acid 
• 267661-15-4 Acetic acid (3S,6S,8S,8aS)-6-benzyl-3-hydroxymethyl-8-methoxy-5-oxo-octahydro-indolizin-6-yl ester 
• 267661-35-8 Acetic acid (3S,6S,8S,8aS)-6-benzyl-3-formyl-8-methoxy-5-oxo-octahydro-indolizin-6-yl ester 

Relevant articles and documents

Synthesis of diversely functionalized indolizidinones and related bicyclic lactams using intramolecular Grubbs olefin metathesis and Dieckmann condensation

Bicyclic 1-aza-2-oxo ring systems with versatile functionality were synthesized from the Grubbs olefin metathesis of appropriate olefinic precursors, starting with L-pyroglutamic acid. The carbocyclization products were further functionalized utilizing th