613241-84-2

Basic information

• Product Name: (1S,5S,8S)-4,4,8-trimethyl-2,3-dioxabicyclo[3.3.1]nonan-8-yl hydroperoxide
• Synonyms: (1S,5S,8S)-4,4,8-trimethyl-2,3-dioxabicyclo[3.3.1]nonan-8-yl hydroperoxide
• CAS NO: 613241-84-2
• Molecular Weight: 202.251
• Mol File: 613241-84-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1S,5S,8S)-4,4,8-trimethyl-2,3-dioxabicyclo[3.3.1]nonan-8-yl hydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5S,8S)-4,4,8-trimethyl-2,3-dioxabicyclo[3.3.1]nonan-8-yl hydroperoxide(613241-84-2)
• EPA Substance Registry System: (1S,5S,8S)-4,4,8-trimethyl-2,3-dioxabicyclo[3.3.1]nonan-8-yl hydroperoxide(613241-84-2)

Safety Data

• Hazardous Substances Data: 613241-84-2(Hazardous Substances Data)

Upstream product

• 617-86-7 triethylsilane 
• 5989-54-8 (-)-(S)-limonene 
• 776-76-1 methyldiphenylsilane 

Relevant articles and documents

Co-catalyzed autoxidation of alkene in the presence of silane. The effect of the structure of silanes on the efficiency of the reaction and on the product distribution

A systematic investigation of the structural effect of silanes on the Co-catalyzed reductive oxygenation of alkene in the presence of silane (Mukaiyama-Isayama reaction) showed that the efficiency of the reaction decreases with the increase of the steric bulk of the silanes. A similar trend was observed for the metal-exchange reaction between Co(III)-alkylperoxo complex and silane, too. The peroxidation of (S)-limonene, followed by deprotection of the derived silyl peroxides, provides a mixture of the corresponding monocyclic hydroperoxide 24 and the bicyclic one 25, the ratio being a marked function of the steric bulk of silanes.