6138-88-1Relevant academic research and scientific papers
Wittig rearrangement of 3-furylmethyl ethers: Facile synthesis of 3-metyl-2-furylmethanols and 3-furylethanols
Tsubuki, Masayoshi,Okita, Hiroyuki,Kaneko, Kazunori,Shigihara, Atsushi,Honda, Toshio
, p. 433 - 444 (2009)
Wittig rearrangement of 3-furylmethyl ethers 1a-i was investigated. Deprotonation of 3-furylmethyl ethers 1a-i with bases, such as BuLi and LDA, occurred preferentially at the allylic, propargylic, benzylic positions and α-position adjacent to carbonyl gr
A new simple route to furanic ketones; preparation of elsholtzione naginata ketone and perilla ketone
Cahiez,Chavant,Metais
, p. 5245 - 5248 (2007/10/02)
Copper- or iron-catalyzed acylation of organomanganese reagents allows to obtain 3- and 2-acylfurans in high yields. Elsholtzione, naginata ketone and perilla ketone have been prepared according to this procedure.
A NEW AND SHORT SYNTHESIS OF DEHYDROELSHOLTZIONE (NAGINATA KETONE) AND ISOEGOMAKETON
Pillot, Jean-Paul,Bennetau, Bernard,Dunogues, Jacques,Calas, Raymond
, p. 4717 - 4720 (2007/10/02)
1-Trimethylsilyl 2-methyl 1-propene and 1-trimethylsilyl 3-methyl 1-butene are useful intermediates for the synthesis of furan natural compounds such as Naginata ketone and isoegomaketone.
