614-43-7

Basic information

• Product Name: 2-Fluoroethyl=benzoate
• Synonyms: 2-Fluoroethyl=benzoate
• CAS NO: 614-43-7
• Molecular Formula: C₉H₉FO₂
• Molecular Weight: 168.1649632
• Mol File: 614-43-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 225.9°C at 760 mmHg
• Flash Point: 88°C
• Appearance: /
• Density: 1.126g/cm³
• Vapor Pressure: 0.0844mmHg at 25°C
• Refractive Index: 1.485
• CAS DataBase Reference: 2-Fluoroethyl=benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Fluoroethyl=benzoate(614-43-7)
• EPA Substance Registry System: 2-Fluoroethyl=benzoate(614-43-7)

Safety Data

• Hazardous Substances Data: 614-43-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H9FO2/c10-6-7-12-9(11)8-4-2-1-3-5-8/h1-5H,6-7H2

Upstream product

• 1049103-26-5 N,N-diethyl benzamide diethyl acetal 
• 1696-17-9 N,N-diethylbenzamide 
• 94-33-7 C₉H₁₀O₃ 
• 309-88-6 hexafluoropropene-diethylamine adduct 
• 371-62-0 2-fluoroethanol 
• 65-85-0 benzoic acid 
• 98-88-4 benzoyl chloride 
• 939-55-9 2-chloroethyl benzoate 

Relevant articles and documents

1,3-Dibromo-5,5-dimethylhydantoin as a Precatalyst for Activation of Carbonyl Functionality

Activation of carbonyl moiety is one of the most rudimentary approaches in organic synthesis and is crucial for a plethora of industrial-scale condensation reactions. In esterification and aldol condensation, which represent two of the most important reactions, the susceptibility of the carbonyl group to nucleophile attack allows the construction of a variety of useful organic compounds. In this context, there is a constant need for development of and improvement in the methods for addition-elimination reactions via activation of carbonyl functionality. In this paper, an advanced methodology for the direct esterification of carboxylic acids and alcohols, and for aldol condensation of aldehydes using widely available, inexpensive, and metal-free 1,3-dibromo-5,5-dimethylhydantoin under neat reaction conditions is reported. The method is air- and moisture-tolerant, allowing simple synthetic and isolation procedures for both reactions presented in this paper. The reaction pathway for esterification is proposed and a scale-up of certain industrially important derivatives is performed.

Selective mono-fluorination of diols via a cyclic acetal of N,N-diethyl-4-methoxybenzamide

Selective mono-fluorination of 1,2- and 1,3-diols was achieved using N,N-diethyl-4-methoxybenzamide diethyl acetal and Et3N-3HF. The reaction proceeds through a cyclic acetal of the benzamide, and only one hydroxy group was fluorinated and anot

CHEMOSELECTIVE FLUORINATION FOR PRIMARY ALCOHOLS

Primary alcohols and their silylated derivatives are selectively fluorinated by tetraalkylammonium fluoride and aryl (or alkyl) sulfonyl fluoride.