61501-39-1Relevant academic research and scientific papers
COUNTERION EFFECTS ON GEOMETRIC CONTROL IN THE PETERSON REACTION OF BISTRIMETHYLSILYL ESTERS: SYNTHETIC SCOPE AND MECHANISTIC IMPLICATIONS
Boeckman, Robert K.,Chinn, Richard L.
, p. 5005 - 5008 (1985)
An interesting and useful level of geometric control can be realized in the reaction of enolates derived from bistrimethylsilyl acetates and aldehydes leading to α-trimethylsilyl esters and derived compounds depending upon the cation employed.Mechanistic
Chiral ligand-controlled asymmetric conjugate addition of lithium amides to enoates
Doi, Hirohisa,Sakai, Takeo,Iguchi, Mayu,Yamada, Ken-ichi,Tomioka, Kiyoshi
, p. 2886 - 2887 (2007/10/03)
The external chiral ligand-controlled asymmetric conjugate addition reaction of lithium amides with α,β-unsaturated esters provided β-amino esters in high yields and high enantioselectivities. Copyright
