615541-06-5

Upstream product

• 3615-41-6 L-Rhamnose 
• 98-88-4 benzoyl chloride 

Downstream Products

• 194411-62-6 1,5-anhydro-2,3,4-tri-O-benzoyl-6-deoxy-L-arabino-hex-1-enitol(3,4-di-O-benzoyl-2-benzoyloxy-L-rhamnal) 
• 194347-80-3 isopropyl 3,4-di-O-benzoyl-6-deoxy-β-L-arabino-hexopyranosid-2-ulose 
• 194347-71-2 3,4-di-O-benzoyl-6-deoxy-α-L-arabino-hexopyranos-2-ulosyl bromide 
• 61198-82-1 2,3,4-tri-O-benzoyl-6-deoxy-α-L-glucopyranosyl bromide 

Relevant academic research and scientific papers

Efficient generation of β-L-rhamnosidic linkages by the 2-ulosyl donor approach: Synthesis of a trisaccharide with a central β-L-rhamnose unit

Practical procedures for the production of variously blocked 6-deoxy-α-L-arabino-2-ketohexosyl bromides from L-rhamnose have been developed. These compounds are highly useful as indirect β-L-rhamnosyl donors: they undergo β-specific glycosidations under Koenigs-Knorr conditions, and the 2-keto group of the resulting 6-deoxy-β-L-hexosiduloses is reduced with high β-L-rhamno selectivity. The straightforward application of this 2-ulosyl donor approach for the synthesis of β-L-rhamnose-containing di- and trisaccharides is demonstrated. ( Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).