615558-48-0

Basic information

• Product Name: Benzamide, 3-hydroxy-N-methoxy-N-methyl-
• CAS NO: 615558-48-0
• Molecular Formula: C9H11NO3
• Molecular Weight: 181.191
• Mol File: 615558-48-0.mol

Chemical Properties

• CAS DataBase Reference: Benzamide, 3-hydroxy-N-methoxy-N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 3-hydroxy-N-methoxy-N-methyl-(615558-48-0)
• EPA Substance Registry System: Benzamide, 3-hydroxy-N-methoxy-N-methyl-(615558-48-0)

Safety Data

• Hazardous Substances Data: 615558-48-0(Hazardous Substances Data)

Upstream product

• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 99-06-9 3-Carboxyphenol 
• 615558-47-9 3-(benzyloxy)-N-methoxy-N-methylbenzamide 

Downstream Products

• 850056-55-2 3-(2-pyridinylmethyloxy)-N-methoxy-N-methylbenzamide 
• 616196-29-3 3-(allyloxy)-N-methoxy-N-methylbenzamide 
• 84476-51-7 3-(4'-chlorobenzyloxy)-N-methoxy-N-methylbenzamide 
• 616196-26-0 N-methoxy-3-(methoxymethoxy)-N-methylbenzamide 
• 13020-57-0 3-hydroxybenzophenone 
• 103203-53-8 3-hydroxy-4'-methoxybenzophenone 
• 21084-29-7 4'-trifluoromethyl-3-hydroxy-benzophenone 
• 566899-68-1 (3-hydroxy-phenyl)-(3-methoxy-phenyl)-methanone 
• 103323-37-1 1-(3-hydroxy-phenyl)-2-methyl-propan-1-one 
• 62810-51-9 1-(3-hydroxyphenyl)pentan-1-one 

Relevant articles and documents

Enantioselective synthesis of 3-substituted dihydrobenzofurans through iridium-catalyzed intramolecular hydroarylation

Intramolecular hydroarylationviaC-H activation is one of the most powerful methods to synthesize carbo- and heterocyclic compounds, whereas we still have room for developing a highly enantioselective variant of the reaction. Here we describe Ir-catalyzed enantioselective intramolecular hydroarylation ofm-allyloxyphenyl ketones. The enantioselective cyclization was efficiently catalyzed by a cationic iridium complex coordinated with a conventional chiral bisphosphine ligand to give benzofurans in high yields with high enantioselectivity. A carbonyl group of ketones functioned as an effective directing group for the C-H activation. In terms of synthetic utility, we also achieved one-pot synthesis of chiral 3-substituted dihydrobenzofurans from readily available allylic carbonates andm-hydroxyacetophenonesviasequential Pd-catalyzed allylic substitution and Ir-catalyzed intramolecular hydroarylation.

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