61586-06-9Relevant academic research and scientific papers
SYNTHESE UND REAKTIONSVERHALTEN ASYMMETRISCHER METALLACYCLEN DES PALLADIUMS UND PLATINS
Abicht, Hans-Peter,Issleib, Kurt
, p. 201 - 214 (2007/10/02)
The preparation, properties and the complexation behaviour of o-lithiobenzyldiorganoarsines are described.Halogen-bridged binuclear complexes of the type (M=Pd, Pt; E=N, P) react with o-LiC6H4CH2ER2 (E=N, P, As), to form asymmetric metallacycles
CYCLOMETALLIERTE Pd- UND Pt-KOMPLEXE DER (o-LITHIOBENZYL)DIORGANOPHOSPHINE
Abicht, Hans-Peter,Issleib, Kurt
, p. 265 - 276 (2007/10/02)
The (o-lithiobenzyl)diorganophosphines o-LiC6H4CH2PR2 (R = Ph, Me, t-Bu) form the corresponding cyclometalated complexes when allowed to react with MCl2*2 Et2S (M = Pd, Pt).Under our reaction conditions they appear to be formed in the cis-form only.Mixed cyclometalated species are described as well as the behaviour of some cyclometalated compounds towards HCl, Br2 and HgBr2 and reactions with n-BuLi.The IR and NMR spectra of the prepared complexes are discussed.
